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Improved photocatalytic reduction of mercuric cations over g-C 3 N 4 nanosheets decorated by mesoporous Bi 2 S 3 nanoparticles under visible light illumination
Applied Nanoscience Pub Date : 2021-01-15 , DOI: 10.1007/s13204-020-01662-x
Maha Alhaddad , M. H. H. Mahmoud

In this context, g-C3N4 nanosheets were decorated by mesoporous Bi2S3 nanoparticles (NPs) to produce newly Bi2S3/g-C3N4 heterojunctions containing various proportions (1, 2, 3, 4 wt.%) of Bi2S3 NPs. This was established using a hard and soft template. The fabricated heterojunctions succeeded to achieve highly efficient elimination of Hg2+ via photocatalytic reduction when illuminated by visible light. Furthermore, the synthesized heterojunctions acquired improved features such as limited band gap energy and significant specific surface areas. The homogenous distribution of the spherical-like Bi2S3 NPs (particle dimension of 3–6 nm) on g-C3N4 nanosheets was declared from the transmission electron microscopy (TEM) technique. The improved Bi2S3/g-C3N4 nanocomposite of 4 wt.% Bi2S3 NPs acquired enlarged magnetization magnitude (35.5 emu g–1) in comparison to that of Bi2S3 NPs (30.5 emu g–1). Tremendous efficiency of the elimination of Hg2+ via photocatalytic reduction has been accomplished by the prepared Bi2S3/g-C3N4 heterojunction in comparison to those by Bi2S3 NPs or g-C3N4 nanosheets. Complete (100%) elimination of Hg2+ has been established by 4 wt.% Bi2S3/g-C3N4 photocatalyst whereas, the efficiency attained over Bi2S3 NPs was 24% after 1 h of visible light illumination. Moreover, the rate of the photocatalytic elimination of Hg2+ by 4 wt.% Bi2S3/g-C3N4 nanocomposite was greater (490.00 µmolg−1 h−1) compared to the rates depicted over neat Bi2S3 NPs (100.00 µmolg−1 h−1) and neat g-C3N4 (65.00 µmolg−1 h−1). In addition, recycled mesoporous Bi2S3/g-C3N4 heterojunctions proposed more excellent stability and durability towards the photocatalytic reduction of mercuric cations.



中文翻译:

在可见光照射下,由介孔Bi 2 S 3纳米粒子修饰的gC 3 N 4纳米片上光催化还原汞阳离子

在这种情况下,用介孔Bi 2 S 3纳米颗粒(NPs)装饰gC 3 N 4纳米片,以产生新的Bi 2 S 3 / gC 3 N 4异质结,其中含有不同比例的(1、2、3、4 wt。%) Bi 2 S 3 NP。这是使用硬模板和软模板建立的。制备的异质结成功实现了Hg 2+的高效消除通过可见光照射时的光催化还原。此外,合成异质结获得了改进的功能,例如有限的带隙能量和显着的比表面积。球形电子Bi 2 S 3 NPs(颗粒尺寸为3–6 nm)在gC 3 N 4纳米片上的均匀分布由透射电子显微镜(TEM)技术证明。该改进的Bi 2小号3 / GC 3 Ñ 4的纳米复合材料的4重量%的Bi 2小号3的NP后天放大磁化大小(35.5鸸鹋克-1相较于的Bi)2S 3 NP(30.5 emu g –1)。与Bi 2 S 3 NP或gC 3 N 4纳米片相比,通过制备的Bi 2 S 3 / gC 3 N 4异质结已经实现了通过光催化还原消除Hg 2+的巨大效率。已经通过4重量%的Bi 2 S 3 / gC 3 N 4光催化剂建立了完全(100%)的Hg 2+消除,而效率高于Bi 2 S 3。可见光照射1 h后,NPs为24%。此外,与纯Bi 2 S 3 NPs相比,通过4 wt。%Bi 2 S 3 / gC 3 N 4纳米复合材料光催化消除Hg 2+的速率更大(490.00 µmolg -1  h -1)。(100.00μmolg -1  h -1)和纯gC 3 N 4(65.00μmolg -1  h -1)。另外,再生介孔Bi 2 S 3 / gC 3 N 4 异质结提出了对光催化还原汞阳离子更优异的稳定性和耐久性。

更新日期:2021-01-15
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