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Pyridazine-bridged expanded rosarin and semi-rosarinogen
Chemical Communications ( IF 4.3 ) Pub Date : 2021-1-8 , DOI: 10.1039/d0cc07433k
Kui Xu 1, 2, 3, 4 , Xiaoshuai Zhang 4, 5, 6, 7 , Guopeng Liu 1, 2, 3, 4 , Wanzun Ma 1, 2, 3, 4 , Yu Yin 1, 2, 3, 4 , Ying Yin 4, 5, 6, 7 , Xi Chen 1, 2, 3, 4 , Xinyun Zhao 1, 2, 3, 4 , Jonathan L. Sessler 8, 9, 10, 11 , Zhan Zhang 1, 2, 3, 4
Affiliation  

The synthesis of the pyridazine-bridged expanded rosarin 1 and a reduced precursor, semi-rosarinogen 2, is reported. A single crystal X-ray diffraction analysis of 1 and theoretical calculations show that both 1 and 2 have distorted structures. Expanded rosarin 1 and its precursor 2 can differentiate various thiols in organic solvents by means of species-specific colour changes and reaction times.

中文翻译:

哒嗪桥接的罗沙林和半玫瑰香原

据报道,哒嗪桥联的膨胀罗沙林1和还原的前体半玫瑰​​香原2的合成。1的单晶X射线衍射分析和理论计算表明1和2都具有扭曲的结构。膨胀的rosarin 1及其前体2可以通过物种特异性的颜色变化和反应时间来区分有机溶剂中的各种硫醇。
更新日期:2021-01-14
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