Pyridazine-bridged expanded rosarin and semi-rosarinogen,Chemical Communications

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Pyridazine-bridged expanded rosarin and semi-rosarinogen
Chemical Communications ( IF 4.3 ) Pub Date : 2021-1-8 , DOI: 10.1039/d0cc07433k
Kui Xu _{1,

2,

3,

4} , Xiaoshuai Zhang _{4,

5,

6,

7} , Guopeng Liu _{1,

2,

3,

4} , Wanzun Ma _{1,

2,

3,

4} , Yu Yin _{1,

2,

3,

4} , Ying Yin _{4,

5,

6,

7} , Xi Chen _{1,

2,

3,

4} , Xinyun Zhao _{1,

2,

3,

4} , Jonathan L. Sessler _{8,

9,

10,

11} , Zhan Zhang _{1,

2,

3,

4}

Affiliation

The synthesis of the pyridazine-bridged expanded rosarin 1 and a reduced precursor, semi-rosarinogen 2, is reported. A single crystal X-ray diffraction analysis of 1 and theoretical calculations show that both 1 and 2 have distorted structures. Expanded rosarin 1 and its precursor 2 can differentiate various thiols in organic solvents by means of species-specific colour changes and reaction times.

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