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Aziridination of Internal Alkenes Using Primary Alkyl Amines in a Microflow Electrocell
Chem ( IF 19.1 ) Pub Date : 2021-01-14 , DOI: 10.1016/j.chempr.2020.12.013 Jiajia Yu , Jie Wu
中文翻译:
在微流电池中使用伯烷基胺对内部烯烃进行氮化。
更新日期:2021-01-14
Chem ( IF 19.1 ) Pub Date : 2021-01-14 , DOI: 10.1016/j.chempr.2020.12.013 Jiajia Yu , Jie Wu
Aziridines are versatile synthetic intermediates en route to structurally diverse and complex nitrogen-containing molecules. In this issue of Chem, Noël and co-workers report the aziridination of internal alkenes with primary alkyl amines through novel electrochemical activation with hydrogen gas generated as the byproduct, assisted by a microflow electrocell.
中文翻译:
在微流电池中使用伯烷基胺对内部烯烃进行氮化。
氮丙啶是通向结构多样且复杂的含氮分子的通用合成中间体。在此期《化学》杂志上,Noël及其同事报道了在微流电池的辅助下,通过新产生的副产物氢气进行电化学活化,将内部烯烃与伯烷基胺进行叠氮化。