A self-assembled tetrathiafulvalene box,Organic Chemistry Frontiers

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A self-assembled tetrathiafulvalene box
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2021-1-8 , DOI: 10.1039/d0qo01543a
Serhii Krykun _{1,

2,

3,

4,

5} , Vincent Croué _{1,

2,

3,

4,

5} , Olivier Alévêque _{1,

2,

3,

4,

5} , Eric Levillain _{1,

2,

3,

4,

5} , Magali Allain _{1,

2,

3,

4,

5} , Cécile Mézière _{1,

2,

3,

4,

5} , Vincent Carré _{6,

7,

8,

9,

10} , Frédéric Aubriet _{6,

7,

8,

9,

10} , Zoia Voïtenko _{11,

12,

13} , Sébastien Goeb _{1,

2,

3,

4,

5} , Marc Sallé _{1,

2,

3,

4,

5}

Affiliation

A M₈L₂ metalla-cage constructed through coordination-driven self-assembly from a quinonato bis-ruthenium complex and an electron-rich tetrathiafulvalene (TTF) tetrapyridyl ligand is depicted. In this molecular box, both TTF units are highly bent and are separated by a distance as short as 3.48 Å in the solid state. This system offers a unique opportunity to study the electronic interactions occurring between two TTF units facing each other in a conformationally rigid environment.

中文翻译：

自组装四硫富瓦烯盒

描述了由喹诺酮双钌配合物和富电子的四硫富瓦烯（TTF）四吡啶基配体通过协调驱动的自组装构建的AM ₈ L ₂金属笼。在此分子盒中，两个TTF单元都高度弯曲，并且在固态状态下相隔的距离短至3.48Å。该系统提供了独特的机会来研究在构象严格的环境中彼此面对的两个TTF单元之间发生的电子相互作用。

更新日期：2021-01-13

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