We observe an anomalous liquid expansion after quenching a binary mixture at coexistence to low pressures in the vapor phase by numerical calculations. This evaporation-induced expansion can be attributed to the pressure imbalance near the liquid-vapor interface, which originates from the interplay between the complex thermodynamics of binary mixtures both in the vapor and liquid phases, as well as their dynamical asymmetries. In addition, careful modulation of the pressure quench in the vapor phase can result in spinodal bubble formation inside liquid phase. The results indicate that the thermodynamics-kinetics interplay could foster our fundamental understanding of the evaporation process and promote its practical applications.

中文翻译：

---

蒸发引起的二元混合物中的液体膨胀和气泡形成

我们通过数值计算观察到，在气相中低压共存的二元混合物淬灭后，液体膨胀异常。蒸发引起的膨胀可归因于液-气界面附近的压力失衡，其源于汽相和液相中二元混合物的复杂热力学之间的相互作用以及它们的动力学不对称性。另外，对蒸气相中的压力骤冷的仔细调节会导致在液相内部形成旋节线气泡。结果表明，热力学与动力学的相互作用可以增进我们对蒸发过程的基本认识，并促进其实际应用。