This highlight review describes the recent development of an electrophile-triggered 1,2-metallate rearrangement of organoboronic ester ate-complex, which proceeds through 1,2-difunctionalization of carbon–carbon σ- and π-bonds, using strain energy as a driving force. Coupling reactions of small ring carbocyclic boronic esters, such as cyclopropyl-, bicyclo[1.1.0]butyl-, and cyclopropenyl-boronic ester, are summarized along with the proposed reaction mechanisms and representative examples.

中文翻译：

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通过1,2-金属盐重排使有机原虫复杂的C-Cσ和π键的应力释放双官能化

这篇重要的综述描述了有机硼酸酯复合物的亲电触发的1,2-金属盐重排的最新进展，该过程通过使用应变能作为驱动力，通过碳-碳σ-键和π-键的1,2-双官能化来进行力。总结了小环碳环硼酸酯，例如环丙基-，双环[1.1.0]丁基-和环丙烯基-硼酸酯的偶联反应，并提出了反应机理和代表性实例。