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Promoting effect of Sb on the selective catalytic reduction of NO with NH3 over CeVO4 catalyst
Journal of the Energy Institute ( IF 5.7 ) Pub Date : 2021-01-13 , DOI: 10.1016/j.joei.2021.01.003
Gui-lin Wu , Rui-tang Guo , Yuan-zhen Liu , Chao-peng Duan , Yu-fang Miao , Jing-wen Gu , Wei-guo Pan

A series of Sb-doped CeVO4 samples were synthetized by hydrothermal method and used in selective catalytic reduction of NO with NH3. Contrasted with other catalysts, Sb2CeVO4 possessed superior NH3-SCR activity and excellent SO2 tolerance. Besides, the characterization results testified that Sb species in Sb2CeVO4 could reduce the crystallization of CeVO4, and improve the surface acidity and reducibility. Moreover, the existence of Sb3+ was beneficial to generate more surface adsorbed oxygen species. Based on the in situ DRIFT spectra, more ad-NH3 and ad-NOx species with higher reactivity were obtainable on Sb2CeVO4 catalyst compared with that on CeVO4 catalyst, which also contributed to enhancing the SCR activity by Langmuir-Hinshelwood (L-H) mechanism effectively.



中文翻译:

Sb对CeVO 4催化剂上NH 3选择性催化还原NO的促进作用

通过水热法合成了一系列掺Sb的CeVO 4样品,并用于NH 3选择性催化还原NO 。与其他催化剂相比,Sb 2 CeVO 4具有优异的NH 3 -SCR活性和出色的SO 2耐受性。此外,表征结果证实,以Sb的Sb物种2 CEVO 4可以减少CEVO的结晶4,和提高表面酸度和还原性。而且,Sb 3+的存在有利于产生更多的表面吸附氧。基于原位DRIFT光谱,更多ad-NH3和广告-NO X与较高反应性的物种是对可获得的Sb 2 CEVO 4与上CEVO比较催化剂4催化剂,这也有助于提高由朗缪尔-欣谢尔伍德(LH)机制有效的SCR活性。

更新日期:2021-01-22
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