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Adsorption and regeneration on iron-activated biochar for removal of microcystin-LR
Chemosphere ( IF 8.8 ) Pub Date : 2021-01-13 , DOI: 10.1016/j.chemosphere.2021.129649
Shengquan Zeng , Eunsung Kan

Novel iron activated biochars (FA-BCs) were prepared via simultaneous pyrolysis and activation of FeCl3-pretreated bermudagrass (BG) for removing microcystin-LR (MC-LR) in aqueous solution. Compared to the raw BC (without activation), the surface area and adsorption capacity of FA-BC at iron impregnation ratio of 2 (2 g FeCl3/g BG) were enhanced from 86 m2/g and 0.76 mg/g to 835 m2/g and 9.00 mg/g. Moreover, FA-BC possessed various iron oxides at its surface which provided the catalytic capacity for regeneration of MC-LR spent FA-BC and magnetic separation after the MC-LR adsorption. Possible mechanisms for the MC-LR adsorption onto FA-BC would include electrostatic attraction, π+-π, hydrogen bond, and hydrophobic interactions. The detailed adsorption studies indicated mainly chemisorption and intra-particle diffusion limitation would participate in the adsorption process. The thermal regeneration at 300 °C kept high regeneration efficiency (99–100%) for the MC-LR spent FA-BC during four cycles of adsorption-regeneration. In addition, the high regeneration efficiency (close to 100%) was also achieved by persulfate oxidation-driven regeneration. FA-BC also exhibited high adsorption capacity for the MC-LR from the real lake water to meet the MC-LR concentration below 1 μg/L as a safe guideline suggested by WHO.



中文翻译:

在铁活化生物炭上吸附和再生以去除微囊藻毒素-LR

通过同时热解和活化FeCl 3预处理的百慕大草(BG)来制备新型的铁活化生物炭(FA-BCs),以去除水溶液中的微囊藻毒素-LR(MC-LR)。与未处理的BC相比(未活化),FA-BC的表面积和吸附能力在铁的浸渍比为2(2 g FeCl 3 / g BG)时从86 m 2 / g和0.76 mg / g提高到835 m 2 / g和9.00 mg / g。此外,FA-BC在其表面具有各种氧化铁,这为MC-LR用过的FA-BC的再生和MC-LR吸附后的磁分离提供了催化能力。MC-LR吸附到FA-BC上的可能机制包括静电吸引π +-π,氢键和疏水相互作用。详细的吸附研究表明,化学吸附和颗粒内扩散限制将主要参与吸附过程。在四个吸附再生循环中,MC-LR废FA-BC的300°C热再生保持了较高的再生效率(99–100%)。此外,通过过硫酸盐氧化驱动的再生,还实现了高再生效率(接近100%)。FA-BC还显示出对真实湖水中MC-LR的高吸附能力,以满足世界卫生组织建议的安全指南,即MC-LR浓度低于1μg/ L。

更新日期:2021-01-24
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