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Encapsulation of Metal Catalysts for Stable Solid Oxide Fuel Cell Cathodes
International Journal of Precision Engineering and Manufacturing-Green Technology ( IF 5.3 ) Pub Date : 2021-01-13 , DOI: 10.1007/s40684-020-00290-8
Jongseo Lee , Mingi Choi , Wonyoung Lee

Metal catalysts have been employed as cathodes for solid oxide fuel cells to facilitate the surface exchange rate in the intermediate temperature range (600–800 °C). However, incorporated metal catalysts easily agglomerate, resulting in the loss of the reaction sites; thus, the electrochemical performance rapidly deteriorates over time. To hinder the agglomeration of metal catalysts while maintaining the catalytic activity, we encapsulated metal catalysts with nano-particulated perovskite materials using an infiltration technique. The encapsulation of Ag nanoparticles with nano-particulated Sm0.5Sr0.5CoO3-δ (SSC) successfully prevented the agglomeration of Ag nanoparticles, maintaining the initial polarization resistance for 200 h at 650 °C, while the polarization resistance of the SSC electrodes with the Ag nanoparticles increased by ~ 190% after 200 h at 650 °C because of the thermal agglomeration of Ag nanoparticles.



中文翻译:

稳定固体氧化物燃料电池阴极金属催化剂的包封

金属催化剂已被用作固体氧化物燃料电池的阴极,以促进中间温度范围(600–800°C)中的表面交换速率。然而,掺入的金属催化剂容易团聚,导致反应位点的损失。因此,电化学性能随时间迅速劣化。为了在保持催化活性的同时阻止金属催化剂的团聚,我们使用渗透技术将金属催化剂与纳米颗粒钙钛矿材料一起包封。纳米颗粒Sm 0.5 Sr 0.5 CoO3 包覆Ag纳米粒子 (SSC)成功地防止了Ag纳米粒子的团聚,在650°C下保持200 h的初始极化电阻,而具有Ag纳米粒子的SSC电极在650°C下200 h后的极化电阻增加了190%。 Ag纳米颗粒的热团聚。

更新日期:2021-01-13
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