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Study of optical interaction between UO2++ and Ho3+ in zinc phosphate glass
Indian Journal of Pure & Applied Physics ( IF 0.6 ) Pub Date : 2021-01-12
Charu Ch Dhondiyal, Himani Tiwari, Tara Bhatt, Hema, Deepak Kumar Upreti, Bhawna Sanwal

A study of Non-radiative energy transfer in UO2-Ho system in zinc phosphate glass has been done by observing the steady state emission of UO2++ with varying concentration of Ho3+ in zinc phosphate glass at room temperature. It has been observed that UO2++ ion emission intensity decreases with increasing Ho3+ concentration resulting in a non-radiative energy transfer from UO2++ to Ho3+. The energy transfer mechanism for the systems is confirmed to be electric dipole-dipole in nature according to Fong-Diestler’s, Forster and Dexter’s and Van Uitert’s theory. The donor-acceptor distances (DD→A) and transfer efficiencies (η), as well as energy transfer probabilities (Pda) in presence of different acceptor concentration, have been calculated.

中文翻译:

磷酸锌玻璃中UO2 ++与Ho3 +的光学相互作用的研究

通过观察室温下磷酸锌玻璃中不同浓度的Ho 3+引起的UO 2 ++的稳态发射,研究了磷酸锌玻璃中UO 2 -Ho系统的非辐射能传递。已经观察到,随着Ho 3+浓度的增加,UO 2 ++的离子发射强度降低,导致从UO 2 ++到Ho 3+的非辐射能量转移。根据Fong-Diestler,Forster和Dexter和Van Uitert的理论,该系统的能量传递机制实际上是电偶极-偶极子。供体-受体距离(D D→A)和转移效率(η)以及在不同受体浓度下的能量转移概率(P da)已被计算。
更新日期:2021-01-12
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