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Production and Polymerization of Biobased Acrylates and Analogs
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2021-01-12 , DOI: 10.1002/marc.202000530
Hugo Fouilloux 1 , Christophe M Thomas 1
Affiliation  

To prepare biobased polymers, particular attention must be paid to the obtention of the monomers from which they are derived. (Meth)acrylates and their analogs constitute such a class of monomers that have been extensively studied due to the wide range of polymers accessible from them. This review therefore aims to highlight the progresses made in the production and polymerization of (meth)acrylates and their analogs. Acrylic acid production from biomass is close to commercialization, as three different high‐potential intermediates are identified: glycerol, lactic acid, and 3‐hydroxypropionic acid. Biobased methacrylic acid is less common, but several promising options are available, such as the decarboxylation of itaconic acid or the dehydration of 2‐hydroxyisobutyric acid. Itaconic acid is also a vinylic monomer of great interest, and polymers derived from it have already found commercial applications. Methylene butyrolactones are promising monomers, obtained from bioresources via three different intermediates: levulinic, succinic, or itaconic acid. Although expensive, methylene butyrolactones have a strong potential for the production of high‐performance polymers. Finally, β‐substituted acrylic monomers, such as cinnamic, fumaric, muconic, or crotonic acid, are also examined, as they provide an original access to biobased materials from various renewable raw materials, such as protein waste, lignin, or wastewater.

中文翻译:

生物基丙烯酸酯和类似物的生产和聚合

为了制备生物基聚合物,必须特别注意衍生它们的单体的存在。(甲基)丙烯酸酯及其类似物构成一类这类单体,由于可从中获得广泛的聚合物,因此已被广泛研究。因此,本综述旨在突出(甲基)丙烯酸酯及其类似物的生产和聚合进展。由生物质生产丙烯酸的工业化已接近尾声,因为已鉴定出三种不同的高潜力中间体:甘油,乳酸和3-羟基丙酸。生物基甲基丙烯酸较少见,但有几种很有希望的选择,例如衣康酸的脱羧或2-羟基异丁酸的脱水。衣康酸也是令人关注的乙烯基单体,以及由其衍生的聚合物已经发现了商业应用。亚甲基丁内酯是有前途的单体,可以通过三种不同的中间体从生物资源中获得:乙酰丙酸,琥珀酸或衣康酸。尽管价格昂贵,但亚甲基丁内酯在生产高性能聚合物方面具有强大的潜力。最后,还对β-取代的丙烯酸单体(例如肉桂酸,富马酸,粘康酸或巴豆酸)进行了检测,因为它们提供了从各种可再生原料(例如蛋白质废物,木质素或废水)中获取生物基材料的原始途径。亚甲基丁内酯具有生产高性能聚合物的强大潜力。最后,还对β-取代的丙烯酸单体(例如肉桂酸,富马酸,粘康酸或巴豆酸)进行了检测,因为它们提供了从各种可再生原料(例如蛋白质废物,木质素或废水)中获取生物基材料的原始途径。亚甲基丁内酯具有生产高性能聚合物的强大潜力。最后,还对β-取代的丙烯酸单体(例如肉桂酸,富马酸,粘康酸或巴豆酸)进行了检测,因为它们提供了从各种可再生原料(例如蛋白质废物,木质素或废水)中获取生物基材料的原始途径。
更新日期:2021-02-05
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