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Polypropylene nonwoven loaded with cerium-doped manganese oxides submicron particles for ozone decomposition and air filtration
Separation and Purification Technology ( IF 8.1 ) Pub Date : 2021-01-12 , DOI: 10.1016/j.seppur.2021.118332
Xiaolong Tang , Yu Dong , Junfu Wei , Zhiyun Kong , Linan Yu , Huan Zhang , Yali Ji

Air pollution caused by particulate matter (PM) and ozone poses a serious threat to human health. The key to eliminating this threat is to develop a multifunctional material with ozone and PM removal capabilities. A novel composite material (Ce-OMS-2/PP-g-AA) composed of surface carboxylation polypropylene nonwoven (PP-g-AA) and cerium-doped manganese oxides particles (Ce-OMS-2) have been prepared by ultraviolet (UV) grafting polymerization and self-assembly methods. The effects of self-assembly processes such as particle concentration and the grafting degree of PP nonwoven were investigated. The Ce-OMS-2/PP-g-AA composite material with a lower average valance of Mn exhibited a stable > 98.82% conversion efficiency for 500 ppb O3 at a relative humidity (RH) of 45%, and a space velocity of 600 L·g−1·h−1 after 36 h at room temperature. Furthermore, the Ce-OMS-2/PP-g-AA composite material achieved a better PM filtration efficiency (80.1%) than the PP-g-AA nonwoven. It was concluded that the Ce-OMS-2/PP-g-AA composite nonwoven could be applied in personal protection and air purification in a complex contaminant environment involving ozone and PM.



中文翻译:

载有铈掺杂的氧化锰亚微米颗粒的聚丙烯无纺布,用于臭氧分解和空气过滤

由颗粒物(PM)和臭氧引起的空气污染严重威胁着人类健康。消除这种威胁的关键是开发一种具有臭氧和PM去除功能的多功能材料。通过表面羧化聚丙烯无纺布(PP-g-AA)和掺铈的氧化锰颗粒(Ce-OMS-2)组成了一种新型复合材料(Ce-OMS-2 / PP-g-AA)。 UV)接枝聚合和自组装方法。研究了PP非织造布的自组装过程如颗粒浓度和接枝度的影响。Mn的平均价数较低的Ce-OMS-2 / PP-g-AA复合材料在相对湿度(RH)为45%时的500 ppb O 3上具有稳定的> 98.82%的转化效率。 600升·克-1 ·h -1在室温下36 h后。此外,Ce-OMS-2 / PP-g-AA复合材料比PP-g-AA非织造布具有更好的PM过滤效率(80.1%)。结论是,Ce-OMS-2 / PP-g-AA复合无纺布可用于涉及臭氧和PM的复杂污染物环境中的个人防护和空气净化。

更新日期:2021-01-19
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