An efficient and convenient method for the synthesis of structurally unique and highly functionalized aryl 2-bromo-2-chloro-1,1-difluoroethyl ethers has been developed. This approach exhibits a broad reaction scope, a simple operation and without the need of any expensive transition-metal catalyst, highly toxic or corrosive reagents. Notably, we demonstrate the potential utility of halothane for the synthesis of aryl gem-difluoroalkyl ethers containing the bromochloromethyl group.

中文翻译：

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通过酚与氟烷之间的碱介导反应合成芳基2-溴-2-氯-1,1-二氟乙基醚

已经开发了一种有效且方便的合成结构独特且高度官能化的芳基2-溴-2-氯-1,1-二氟乙基醚的方法。该方法显示了广泛的反应范围，简单的操作并且不需要任何昂贵的过渡金属催化剂，剧毒或腐蚀性试剂。值得注意的是，我们证明氟烷的芳基合成中的潜在效用宝石含有溴氯甲基-difluoroalkyl醚。