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Novel Acetylene Derivatives of Stable Tetrathiatriarylmethyl Radicals
Russian Journal of Organic Chemistry ( IF 0.8 ) Pub Date : 2021-01-11 , DOI: 10.1134/s1070428020110032 D. V. Trukhin , O. Yu. Rogozhnikova , T. I. Troitskaya , S. S. Ovcherenko , E. V. Amosov , V. M. Tormyshev
中文翻译:
稳定的四硫代三芳基甲基自由基的新型乙炔衍生物
更新日期:2021-01-11
Russian Journal of Organic Chemistry ( IF 0.8 ) Pub Date : 2021-01-11 , DOI: 10.1134/s1070428020110032 D. V. Trukhin , O. Yu. Rogozhnikova , T. I. Troitskaya , S. S. Ovcherenko , E. V. Amosov , V. M. Tormyshev
Abstract
The reactions of aliphatic amines containing terminal acetylene groups with Finland trityl afford its mono-, bi-, and triacetylene derivatives. These derivatives are valuable reagents for targeted insertion of spin labels via the CuAAC click reaction.
中文翻译:
稳定的四硫代三芳基甲基自由基的新型乙炔衍生物
摘要
含有末端乙炔基的脂族胺与芬兰三苯甲基的反应得到其单,联和三乙炔衍生物。这些衍生物是有价值的试剂,可通过CuAAC点击反应定向插入旋转标记。