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Synthesis of three-dimensional graphene architectures from chicken feather and its unusual dimensional crossover in electronic conductivity
Nano-Structures & Nano-Objects Pub Date : 2021-01-08 , DOI: 10.1016/j.nanoso.2020.100665
Debabrata Nandi , Jyotishkumar Parameswaranpillai , Suchart Siengchin

Three-dimensional graphene architectures were synthesized from a new source, chicken feather, a bio-waste. Here ferric chloride (FeCl3) was used as a self-originator template, with a high C/O ratio (21:1). The introduction of Fe3+ ion into the activated frame of carbon generated graphene nanostructure. X-ray photoelectron spectroscopy was used to analyse the defects in the prepared graphene. The obtained structures were found to be unique nanoplatelets and three-dimensional pyramid-like structure. Its DC conductivity has been tested within the temperature range of 20 to 300K and their temperature-dependent conduction mechanism was established. At 100 K and 50 K, a 3D–2D and Mott–ES type cross-over were observed respectively, with varied hopping length. The conductivity was found to be decreased with lowering temperature which was similarly observed in metals.



中文翻译:

鸡毛三维石墨烯结构的合成及其在电导率上的异常跨度

三维石墨烯架构是从一种新的来源鸡羽毛,一种生物废物中合成的。此处,氯化铁(FeCl 3)被用作具有高C / O比(21:1)的自发模板。将Fe 3+离子引入碳生成的石墨烯纳米结构的活化框架中。用X射线光电子能谱分析所制备的石墨烯中的缺陷。发现获得的结构是独特的纳米片和三维金字塔状结构。它的直流电导率已在20至300K的温度范围内进行了测试,并建立了与温度有关的传导机理。在100 K和 分别观察到50 K,3D–2D和Mott–ES型交叉,其跳跃长度不同。发现电导率随温度降低而降低,这在金属中类似地观察到。

更新日期:2021-01-10
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