The complex [Pb(tsac)₂H₂O] has been used as a synthon for the synthesis of a series of lead(II) thiosaccharinate mixed ligand complexes with the tertiary phosphines; PPh₃, Ph₂P(CH₂)_nPPh₂, n = 1, dppm; n = 2, dppe; n = 3, dppp or the heterocyclic; 2-aminobenzothiophene (abtH), 2-acetamidopyrimidine (aampH) and 2-benzimidazolethiol (bimsH). The prepared complexes were characterized using; IR, ¹H-, ³¹P-{¹H} NMR, molar conductivity, elemental analysis in addition, the crystal structure of the complex [Pb₂(tsac)₄(µ-dppe)] was resolved by x-ray diffraction analysis of a single crystal. [Pb₂(tsac)₄(µ-dppe)] crystallizes in the triclinic space group P-1 a = 9.0955(5), b = 11.4197(6), c = 15.3174(7) Å, Z = 2 and refined to R₁ = 0.0422. Herein, thiosaccharine shows the ability to coordinate to lead(II) center in a variety of modes, which are monodentate, chelate- bidentate via a nitrogen atom and/ or a sulfur atom of the thiole group. Furthermore, the complexes [Pb(tsac)₂H₂O] and [Pb₂(tsac)₄(µ-dppe)] were used to examine their ability to store hydrogen. The results show that [Pb(tsac)₂H₂O] and [Pb₂(tsac)₄(µ-dppe)] are able to store 0.29 and 1.12 wt% H₂, respectively.

配合物[Pb（tsac）₂ H ₂ O]已被用作合成子，用于合成一系列硫代糖精铅（II）与叔膦的混合配体。PPh ₃，Ph ₂ P（CH ₂）_n PPh ₂，n ＝ 1，dppm；n = 2，dppe；n = 3，dppp或杂环；2-氨基苯并噻吩（abtH），2-乙酰氨基嘧啶（aampH）和2-苯并咪唑硫醇（bimsH）。所制备的复合物的特征在于：IR，¹ H-，³¹ P- { ¹ H} NMR，摩尔电导率，另外还要进行元素分析，配合物的晶体结构[Pb ₂（tsac）₄（μ-dppe）]通过单晶的X射线衍射分析来解析。[Pb ₂（tsac）₄（µ-dppe）]在三斜晶空间群P-1中结晶，a = 9.0955（5），b = 11.4197（6），c = 15.3174（7）Å，Z = 2并精制为R ₁  ＝ 0.0422。在本文中，硫代糖精显示出以多种模式与铅（II）中心配位的能力，所述模式是单齿的，经由硫醇基团的氮原子和/或硫原子的螯二齿。此外，使用络合物[Pb（tsac）₂ H ₂ O]和[Pb ₂（tsac）₄（μ-dppe）]来检查它们的储氢能力。结果表明[Pb（tsac）₂ H ₂ O]和[Pb ₂（tsac）₄（μ-dppe）]分别能够存储0.29和1.12 wt％的H ₂。