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Layered aluminum tri-polyphosphate as intercalation host for 6-aminohexanoic acid – Synthesis, characterization and application as corrosion protection inhibitor for low carbon steel
Corrosion Science ( IF 8.3 ) Pub Date : 2021-01-08 , DOI: 10.1016/j.corsci.2021.109239
C. Hejjaj , A. Ait Aghzzaf , I. Bouali , R. Hakkou , M. Dahbi , C.B. Fischer

Developing efficient inhibitors based on eco-friendly compounds for steel protection is crucially important. Here the synthesis and characterization of a new hybrid inhibitor based on intercalation of 6-aminohexanoic acid (6-AHA) in layered aluminum tri-polyphosphate (ATP) are reported. ATP and the inorganic-organic hybrid inhibitor system ATP-6-AHA are characterized by XRD, thermal gravimetric analysis (TGA), SEM, IR and Raman spectroscopy. The interlayer space of ATP is expanded by 10.1 Å, with 6-AHA planes arranged in bilayers. Corrosion efficiency of ATP-6-AHA was evaluated in 0.1 M and 3.5 % NaCl using electrochemical impedance spectroscopy (EIS) and showed a significantly reduced corrosion for steel S235.



中文翻译:

层状三聚磷酸铝作为6-氨基己酸的嵌入基质–合成,表征和作为低碳钢腐蚀防护剂的应用

开发基于环保化合物的高效缓蚀剂对钢的保护至关重要。在此报道了基于6-氨基己酸(6-AHA)在层状三聚磷酸铝(ATP)中的嵌入的新型杂化抑制剂的合成和表征。通过XRD,热重分析(TGA),SEM,IR和拉曼光谱对ATP和无机-有机杂化抑制剂体系ATP-6-AHA进行表征。ATP的层间空间扩展了10.1Å,双层中排列了6-AHA平面。使用电化学阻抗谱(EIS)在0.1 M和3.5%NaCl中评估了ATP-6-AHA的腐蚀效率,结果表明S235钢的腐蚀显着降低。

更新日期:2021-01-19
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