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Modification of barrier height and depletion layer width of methyl red (MR) dye-based organic device in the presence of single-walled carbon nanotubes (SWCNT)
Indian Journal of Physics ( IF 1.6 ) Pub Date : 2021-01-10 , DOI: 10.1007/s12648-020-01972-4
Sudipta Sen , N. B. Manik

In this paper, barrier height (\(\phi_{{\text{b}}}\)) and depletion layer width (Wd) of ITO-coated glass/Methyl Red (MR) dye/Aluminum (Al)-based organic device have been studied, and effect of single-walled carbon nanotubes (SWCNT) on both of these parameters has been observed. ITO-coated glass as front electrode and Aluminum as back electrode are used to form the device by using spin coating technique. \(\phi_{{\text{b}}}\) is calculated by analyzing both I–V and C–V characteristics. In the presence of SWCNT, \(\phi_{{\text{b }}}\) is reduced from 0.870 ± 0.05 eV to 0.754 ± 0.05 eV in I–V characteristics and from 0.850 ± 0.12 eV to 0.784 ± 0.12 eV in C–V characteristics. \(\phi_{{\text{b }}}\) is also estimated by Norde method, which shows the presence of SWCNT lowers the value of \(\phi_{{\text{b }}}\) from 0.852 eV to 0.738 eV. Wd has been calculated from C–V characteristics. With SWCNT, value of Wd reduces from (8.74 ± 0.02) × 10−6 cm to (7.85 ± 0.02) × 10−6 cm. Threshold voltage also decreases from 2.52 V to 1.99 V in the presence of SWCNT. Addition of SWCNT within device ameliorates charge injection by lessening \(\phi_{{\text{b}}}\) and Wd of the device.



中文翻译:

在单壁碳纳米管(SWCNT)存在下对基于甲基红(MR)染料的有机器件的势垒高度和耗尽层宽度的修改

在本文中,ITO涂层玻璃/甲基红(MR)染料/铝(Al)基的势垒高度(\(\ phi _ {{\ text {b}}} \)和耗尽层宽度(W d)对有机器件进行了研究,并观察到单壁碳纳米管(SWCNT)对这两个参数的影响。通过旋涂技术,使用ITO涂层玻璃作为前电极,铝作为后电极来形成器件。\(\ phi _ {{\ text {b}}} \)是通过分析I–V和C–V特性来计算的。在存在SWCNT的情况下,\(\ phi _ {{\ text {b}}} \)的I–V特性从0.870±0.05 eV降低到0.754±0.05 eV,而I–V特性从0.850±0.12 eV降低到0.784±0.12 eV。 C–V特性。\(\ phi _ {{\ text {b}}} \)也可以通过Norde方法进行估算,这表明SWCNT的存在将\(\ phi _ {{\ text {b}}} \)的值从0.852 eV降低到0.738 eV。W d由C–V特性计算得出。使用SWCNT,W d的值从(8.74±0.02)×10 -6 cm减小到(7.85±0.02)×10 -6 cm。在存在SWCNT的情况下,阈值电压也从2.52 V降至1.99V。在器件内添加SWCNT可通过减小器件的\(\ phi _ {{\ text {b}}} \)W d来改善电荷注入。

更新日期:2021-01-10
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