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Polaron conduction mechanism in Nickel ferrite and its rare-earth derivatives
Physica B: Condensed Matter ( IF 2.8 ) Pub Date : 2021-01-08 , DOI: 10.1016/j.physb.2021.412819
Kodam Ugendar , G. Markandeyulu , Shanigaram Mallesh

NiFe2O4 & NiFe1.925R0.075O4 (R = Lu, Yb & Y) samples conductivity response for alternating current (σac) in the high temperature region (300 K to 570 K), and for direct current conductivity (σdc) response in the temperature range 80 K–300 K were investigated. For all the investigated samples σac increases with raising frequency owing to transfer of charge carriers at the two octahedral sites containing Fe3+ or Ni2+. The total σac was observed to follow σ = D + Bωn where the frequency exponent n, initially decreases and then increases following overlapping large polaron model. The behaviour of σac with temperature reveals the semiconducting behaviour of the investigated samples. The Arrhenius plots of σac shows two regions of conductivity suggesting two types of relaxation phenomena. The σdc, also increases with increasing temperature, owing to the raise in the thermally stimulated drift mobility of charge carriers. The decrease in the activation energy with decreasing temperature corresponds to small polaron hopping mechanism.



中文翻译:

镍铁氧体及其稀土衍生物中的极化子传导机理

镍铁2Ø4和镍铁1.925 R 0.075 O4 (R = Lu,Yb和Y)采样交流电的电导率响应(σ一种C)在高温区域(300 K至570 K),对于直流电导率(σdC)研究了在80 K–300 K温度范围内的响应。对于所有调查的样本σ一种C由于载流子在两个含有Fe 3+或Ni的八面体位置上的转移而随频率的增加而增加2+。总数σ一种C 被观察到跟随 σ = D + Bωñ频率指数n最初在重叠大极化子模型之后开始降低,然后增加。的行为σ一种C温度的变化揭示了所研究样品的半导体行为。的阿累尼乌斯情节σ一种C显示了两个导电区域,表明两种类型的松弛现象。的σdC由于温度升高,电荷载流子的热激发漂移迁移率也随之增加。活化能随温度降低而降低,对应于较小的极化子跳跃机制。

更新日期:2021-01-08
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