Journal of the Iranian Chemical Society ( IF 2.2 ) Pub Date : 2021-01-08 , DOI: 10.1007/s13738-020-02148-x Pankaj Kosti , Gowhar Ahmad Naikoo , Ratnesh Das , Neha Mishra , Sushil Kashaw
Ten metal complexes of Co2+, Ni2+, Cu2+, Zn2+ and Cd2+ were synthesized by two novel Schiff bases derived from condensation of m-pthalaldehyde with 4-amino benzoic acid and isonicotinic hydrazide. The as-synthesized metal complexes were characterized and explored by different spectroscopic techniques. FT-IR spectra have confirmed the presence of C=N bands as well as UV–Vis spectroscopy in both Schiff bases KM-1 and KM-2. All as-prepared compounds were evaluated for the antimicrobial activities against the Escherichia coli and Propionibacterium acnes. KM-1 and its metal complexes have shown efficient results compared to KM-2. The electrochemical study of M2+ complexes by cyclic voltammograms in electrolyte solution (Pt electrode) demonstrated electrochemically irreversible oxidative and reductive responses.
中文翻译:
由4-氨基苯甲酸和异烟肼合成的席夫碱配体的Co 2+,Ni 2+,Cu 2+,Zn 2+和Cd 2+金属配合物的生物和电化学研究
的Co十金属络合物2+,镍2+,铜2+,锌2+和Cd 2+被来自的缩合衍生的两种新型希夫碱合成米-pthalaldehyde与4-氨基苯甲酸和异烟酰肼。通过不同的光谱技术对合成后的金属配合物进行表征和探索。FT-IR光谱证实了Schiff碱KM-1和KM-2均存在C = N谱带以及UV-Vis光谱。评价所有制备的化合物对大肠杆菌和痤疮丙酸杆菌的抗菌活性。与KM-2相比,KM-1及其金属络合物已显示出有效的结果。M 2+配合物在电解液(Pt电极)中的循环伏安图电化学研究表明,电化学不可逆的氧化和还原反应。