Copper-catalyzed three-component oxycyanation of alkenes,Organic Chemistry Frontiers

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Copper-catalyzed three-component oxycyanation of alkenes
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020-12-25 , DOI: 10.1039/d0qo01437k
Yuehua Zeng _{1,

2,

3,

4,

5} , Yajun Li _{1,

2,

3,

4,

5} , Daqi Lv _{1,

2,

3,

4,

5} , Hongli Bao _{1,

2,

3,

4,

5}

Affiliation

A copper-catalyzed, three-component reaction for the direct oxycyanation of various alkenes with aryl diacyl peroxides and trimethylsilyl cyanide has been developed. Both unactivated alkenes and styrenes are reliable substrates and produce β-cyanohydrin derivatives. An asymmetric version of this reaction has been conducted and proceeds well.

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