当前位置: X-MOL 学术J. Fluoresc. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Designed Synthesis of Fluorescence ‘Turn-on’ Dual Sensor for Selective Detection of Al 3+ and Zn 2+ in Water
Journal of Fluorescence ( IF 2.6 ) Pub Date : 2021-01-06 , DOI: 10.1007/s10895-020-02664-2
Naren Mudi , Paresh Hazra , Milan Shyamal , Samir Maity , Prabhat Kumar Giri , Shashanka Shekhar Samanta , Debkumar Mandal , Ajay Misra

1-(Pyridin-2-yl-hydrazonomethyl)-naphthalen-2-ol (PNOH) is a naphthalene-based fluorescence dual chemo-sensor for Al3+ and Zn2+. The probe (PNOH) is spectroscopically characterised and the chemo-sensing mechanism has been demonstrated through 1H NMR, absorption and both steady state and time resolved fluorescence study. The ‘turn-on’ luminescence property of PNOH is used for the selective detection of trace amount of Al3+and Zn2+via chelation enhanced fluorescence (CHEF) through complex formation. The 1:1 stoichiometry of each sensor-metal complex is observed from Job’s plot based on UV-Vis titration. Most promising advantage of the probe (PNOH) is its application in the one-pot detection of Al3+ (λem- 460 nm) and Zn2+em- 510 nm) exciting at same wavelength (λex- 420 nm) while high intense emission appears at two different wavelengths. Limit of detection (LOD) of PNOH towards Al3+ & Zn2+ are found to be 60 nM & 365 nM respectively. Real water sample analysis has also been demonstrated by using the probe PNOH.



中文翻译:

设计合成用于选择性检测水中Al 3+和Zn 2+的荧光“开启”双传感器

1-(吡啶-2-基-肼基甲基)-萘-2-醇(PNOH)是用于Al 3+和Zn 2+的基于萘的荧光双化学传感器。探针(PNOH)具有光谱学特征,并且通过1 H NMR,吸收以及稳态和时间分辨荧光研究证明了化学感应机理。PNOH的“开启”发光特性用于通过络合物形成的螯合增强荧光(CHEF)选择性检测痕量的Al 3+和Zn 2+。从基于UV-Vis滴定的Job's图中观察到每种传感器-金属配合物的化学计量比为1:1。探针(PNOH)的最有希望的优势是其在Al的一锅法检测中的应用3+(λem-460 nm)和Zn 2+λem -510 nm)在相同波长(λex -420 nm)激发,而高强度发射出现在两个不同的波长。发现PNOH对Al 3+和Zn 2+的检出限(LOD)分别为60 nM和365 nM。使用探针PNOH也已证明了实际水样分析。

更新日期:2021-01-06
down
wechat
bug