We review the O isotope modeling in the atmosphere below 100 km, which is a large and active area of research. Our review will not be exhaustive but instead will highlight some of the key papers on the topic over the past nearly 30 years. We focus our review on modeling the mass-independent fractionation signatures associated with O3 formation and other species that photochemically interact with O3. After a brief discussion of isotopic O3 formation, we present results from models of Δ17O in CO2, OH and H2O, nitrates, sulfates, and...

中文翻译：

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大气中氧同位素的质量无关分馏

我们回顾了100 km以下大气中的O同位素建模，这是一个庞大而活跃的研究领域。我们的综述并不详尽，而是将重点介绍过去近30年中有关该主题的一些关键论文。我们的审查集中在建模与O3形成以及与O3光化学相互作用的其他物种相关的质量无关的分离特征上。在简要讨论了同位素O3的形成之后，我们介绍了来自CO2，OH和H2O，硝酸盐，硫酸盐和水的Δ17O模型的结果。