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Pd‐Catalyzed Negishi Cross‐Coupling of Vinyl Bromides with Diborylmethylzinc Chloride
Bulletin of the Korean Chemical Society ( IF 2.3 ) Pub Date : 2021-01-04 , DOI: 10.1002/bkcs.12212
Minjae Kim 1 , Jun Hee Lee 2 , Seung Hwan Cho 1
Affiliation  

We have developed Pd‐catalyzed Negishi cross‐coupling of diborylmethylzinc chloride with vinyl bromides. The reaction shows a broad scope and an array of α‐boryl‐substituted allylic boronate esters are obtained in high efficiency.
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中文翻译:

Pd催化的乙烯基溴与二硼烷基甲基锌氯化物的Negishi交叉偶联

我们已经开发了二硼烷基甲基氯化锌与乙烯基溴化物在Pd催化下的Negishi交叉偶联。该反应显示出广阔的范围,并且可以高效地获得一系列α-硼基取代的烯丙基硼酸酯。
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更新日期:2021-01-04
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