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Efficient Catalytic Conversion of Polysulfides by Biomimetic Design of “Branch-Leaf” Electrode for High-Energy Sodium–Sulfur Batteries
Nano-Micro Letters ( IF 31.6 ) Pub Date : 2021-01-05 , DOI: 10.1007/s40820-020-00563-6
Wenyan Du 1 , Kangqi Shen 2 , Yuruo Qi 1 , Wei Gao 1 , Mengli Tao 1 , Guangyuan Du 1 , Shu-Juan Bao 1 , Mingyang Chen 3 , Yuming Chen 4 , Maowen Xu 1
Affiliation  

  • 3D “branch-leaf” biomimetic design is proposed for high-performance Na-S batteries.

  • The conductive “branch” can ensure adequate electron and electrolyte supply with the “leaf” can catalyze the conversion of polysulfides.

  • DFT calculation reveals that the Co nanoparticles can enable fast reduction reaction of the polysulfides;

  • The prepared CNF-L@Co/S electrode exhibits a high initial specific capacity of 1201 mAh g−1 at 0.1 C and superior rate performance.



中文翻译:

高能钠硫电池“枝叶”电极仿生设计高效催化转化多硫化物

  • 3D“枝叶”仿生设计被提出用于高性能钠硫电池。

  • 导电“分支”可以保证充足的电子和电解质供应,“叶子”可以催化多硫化物的转化。

  • DFT计算表明,Co纳米颗粒可以使多硫化物快速还原反应;

  • 制备的 CNF-L@Co/S 电极在 0.1 C时具有 1201 mAh g -1的高初始比容量和优异的倍率性能。

更新日期:2021-01-05
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