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Binder and conductive agent‐free electrode for the excellent aqueous asymmetrical supercapacitor
Solid State Sciences ( IF 3.4 ) Pub Date : 2021-01-04 , DOI: 10.1016/j.solidstatesciences.2020.106530
Nighat Zarshad , Jianghua Wu , Anis Ur Rahman , Asad Ali , Ce Qiu , Ruziguli Aisha , Rui Gao , Yu Xie , Henmei Ni

Aimed at improving the electric efficacy of supercapacitor, we designed a novel binder and conductive agent‐free electrode material by integrating varying amounts of aluminum into ultrathin nanosheets of NiCo layer double hydroxide on nickel foam via a one step hydrothermal treatment. We investigated the remarkable impact of Al on the morphology and electrical performance of NiCo2Alx-OH. A transfiguration occurred from β-phase of NiCo2–OH to α-phase of NiCo2Alx-OH with the introduction of Al in NiCo–OH. The NiCo2Al0.5-OH electrode has 1570 F g−1 specific capacitance at a current density of 2 A g−1. A high performance aqueous asymmetric supercapacitor (NiCo2Al0.5-OH//AC) was designed with NiCo2Al0.5-OH as the positive electrode. This device demonstrated an excellent energy density of 56.8 W h kg−1 at 618 W kg−1 power density and 98% capacitance retention over 6000 cycles at a current density of 20 A g−1.



中文翻译:

卓越的水性不对称超级电容器的无粘结剂和无导电剂电极

为了提高超级电容器的电效率,我们设计了一种新颖的无粘合剂和无导电剂的电极材料,通过一步水热处理将不同量的铝整合到泡沫镍泡沫的NiCo层双氢氧化物超薄纳米片中。我们研究了Al对NiCo 2 Al x -OH的形貌和电性能的显着影响。甲变身从发生β镍钴的-PHASE 2 -OH到α镍钴的-PHASE 2的Al X -OH与镍钴-OH引入Al组成。NiCo 2 Al 0.5 -OH电极具有1570 F g -1电流密度为2 A g -1时的比电容。设计了以NiCo 2 Al 0.5 -OH为正极的高性能水性不对称超级电容器(NiCo 2 Al 0.5 -OH // AC)。该器件 在618 W kg -1功率密度下表现出56.8 W h kg -1的出色能量密度,在20 A g -1的电流密度下在6000次循环中具有98%的电容保持率。

更新日期:2021-01-10
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