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Effect of Silicon on Corrosion of Directional Fe-B-Si Alloy in Liquid Zinc
Metallurgical and Materials Transactions A ( IF 2.2 ) Pub Date : 2021-01-02 , DOI: 10.1007/s11661-020-06110-7
Guangzhu Liu , Jingfu Liu , Lili Feng , Yu Kang , Di Yue

The effect of Si on the corrosion of an Fe-B-Si alloy in liquid zinc was investigated. Corrosion tests of Fe-B-Si were conducted in a pure zinc bath (99.99 wt pct Zn). The results indicated that Si in α-Fe phase had a significant effect on the structure and evolution of corrosion interfaces in a directional Fe-B-Si alloy immersed in liquid zinc. Moreover, Si enrichment of the corroded interface induced changes in the mode of element diffusion, thereby affecting the Fe-Zn reaction and the quantity and volume of Fe-Zn compound. The Fe-Zn compound was occluded with the residual Fe2B closest to the corrosion interface, this structure could prevent direct contact between the liquid zinc and the alloy, and firm rooting of the compound at the interface. Therefore, Si in α-Fe phase had a significant effect on the corrosion resistance of Fe-B-Si alloy in liquid zinc. At a Si content of 0.318 wt pct, the densest composite corrosion product layer and highest corrosion resistance were obtained.



中文翻译:

硅对定向锌铁硼硅合金在液态锌中腐蚀的影响

研究了Si对Fe-B-Si合金在液态锌中腐蚀的影响。Fe-B-Si的腐蚀测试在纯锌浴(99.99 wt%的Zn)中进行。结果表明,α-Fe相中的Si对浸入液态锌中的定向Fe-B-Si合金中的腐蚀界面的结构和演变有显着影响。此外,腐蚀界面的Si富集引起元素扩散方式的变化,从而影响Fe-Zn反应以及Fe-Zn化合物的数量和体积。Fe-Zn化合物被残留的Fe 2吸附B最靠近腐蚀界面,这种结构可以防止液态锌与合金之间的直接接触,并防止化合物在界面牢固扎根。因此,α-Fe相中的Si对Fe-B-Si合金在液态锌中的耐蚀性具有显着影响。在Si含量为0.318wt%的情况下,获得了最致密的复合腐蚀产物层和最高的耐腐蚀性。

更新日期:2021-01-02
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