It was well recognized that the pollutant emissions from real-world residential coal combustion contributed significantly to air pollution and human health, resulting in an urgent need for a better understanding of the pollutant emission factors (EFs) of residential coal combustion. However, field-based researches on residential coal combustion emissions are still limited at this stage. In this study, based on carbon balance method, emission factors (EFs) of CO₂ and a series of pollutants, including gaseous pollutants (CO, NO_X, CH₄, and SO₂), particulate matters (PM_2.5 and PM₁₀), elemental carbon (EC), organic carbon (OC), and polycyclic aromatic hydrocarbons (PAHs) from residential honeycomb briquettes (HB) and coal chunks (CC) combustion were measured in real-world cooking stoves. As a result, apart from SO₂, the burning of HB produced much less pollutants than CC. The median of emission reduction ratios estimated from Monte Carlo simulation ranged from 2.4% (SO₂) to 98.8% (EC) by replacing CC with HB in residential combustion in Shanxi province in 2012. EFs of CO, PM_2.5 and PAHs derived from the present field measurement were around 1–50 times higher than those from laboratory tests; furthermore, larger variations were found in our field measurement compared to that in the laboratory studies. This result called for more field measurements to reduce uncertainties of emission inventory estimations. As for the PAHs emissions, particle phase PAHs dominated in both HB and CC burning and PAHs emissions from HB burning had lower toxicity than CC combustion. Hence, HB is an ideal substituted fuel compared with CC. Previous studies suggested that PAHs isomer ratios of FLA/(FLA+PYR) and IcdP/(IcdP+BghiP) above 0.5 represented source of coal combustion, which did not fit with our study well, indicating PAHs isomer ratios might not be valid enough for source apportionment.