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Catalytic Reactions on Pd–Au Bimetallic Model Catalysts
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2020-12-28 , DOI: 10.1021/acs.accounts.0c00642
Sungmin Han 1 , C. Buddie Mullins 1, 2, 3
Affiliation  

The enhanced catalytic activity of Pd–Au catalysts originates from ensemble effects related to the local composition of Pd and Au. The study of Pd–Au planar model catalysts in an ultrahigh vacuum (UHV) environment allows the observation of molecular level catalytic reactions between the Pd–Au surface and target molecules. Recently, there has been progress in understanding the behavior of simple molecules (H2, O2, CO, etc.) employing UHV surface science techniques, the results of which can be applied not only to heterogeneous catalysis but also to electro- and photochemical catalysis.

中文翻译:

Pd-Au双金属模型催化剂上的催化反应

Pd–Au催化剂的增强的催化活性源自与Pd和Au的局部组成有关的整体效应。在超高真空(UHV)环境中对Pd–Au平面模型催化剂的研究可以观察到Pd–Au表面与目标分子之间的分子级催化反应。最近,在利用超高压表面科学技术理解简单分子(H 2,O 2,CO等)的行为方面取得了进展,其结果不仅可以应用于多相催化,而且可以应用于电化学和光化学反应。催化。
更新日期:2021-01-19
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