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Effect of lead and copper containing brine on steel materials for geothermal applications – A corrosion study
Geothermics ( IF 3.5 ) Pub Date : 2020-12-29 , DOI: 10.1016/j.geothermics.2020.102024
Anastasia Stoljarova , Simona Regenspurg , Ralph Bäßler , Troels Mathiesen , Johan Braüner Nielsen

Geothermal brines often contain high amounts of lead and copper ions that can precipitate as native Cu0 and Pb0 as consequence of galvanic corrosion when brines react with carbon steel materials. This contribution evaluates which materials could overcome the problem of galvanic corrosion at geothermal environment.

The behavior of these materials in water containing high chloride concentration (> 100 g/L NaCl) as well as various amounts of dissolved PbCl2 and/or CuCl2 was characterized by electrochemical and exposure measurements.

Both methods reveal carbon steel suffers corrosion susceptibility, accompanied by Cu° and/or Pb° precipitation on the surface. Electrochemical measurements on stainless steels result in significant difference in corrosion and repassivation potentials (Ecorr = −189 mV, Erep =70 mV), indicating a good corrosion resistance.



中文翻译:

含铅和铜的盐水对地热应用钢材的影响–腐蚀研究

地热盐水通常包含大量的铅和铜离子,当盐水与碳钢材料发生反应时,由于电化腐蚀,它们可能会以天然Cu 0和Pb 0的形式沉淀。该贡献评估了哪些材料可以克服地热环境中的电偶腐蚀问题。

这些材料在高氯化物浓度(> 100 g / L NaCl)以及各种溶解的PbCl 2和/或CuCl 2的水中的行为通过电化学和暴露测量来表征。

两种方法都表明碳钢易受腐蚀,并伴有表面上的Cu°和/或Pb°沉淀。不锈钢上的电化学测量结果导致腐蚀和再钝化电位存在显着差异(E corr = -189 mV,E rep = 70 mV),表明具有良好的耐腐蚀性。

更新日期:2020-12-29
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