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High dielectric constant poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) for capacitive pressure and bending sensors
Polymer ( IF 4.1 ) Pub Date : 2020-12-28 , DOI: 10.1016/j.polymer.2020.123349
N. Pereira , S. Gonçalves , J.C. Barbosa , R. Gonçalves , C.R. Tubio , J.L. Vilas-Vilela , C.M. Costa , S. Lanceros-Mendez

Poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene), P(VDF-TrFE-CFE), samples were prepared by solvent casting by varying polymer concentration and solvent evaporation temperature. Different sample morphologies were obtained depending on the processing conditions, as well as different physical-chemical properties such as degree of crystallinity, mechanical and dielectric properties. On the other hand, the electroactive β-phase content and the degradation temperature of the P(VDF-TrFE-CFE) samples are independent of the processing conditions. At 1 kHz, the highest dielectric constant, ε’ = 40, was obtained for the samples prepared with 15 wt% polymer concentration in solutions and processing conditions based on solvent evaporation and polymer melting at 210 °C. Taking into account the high dielectric response, pressure and bending capacitive sensors were developed with excellent response and high sensibility (0.03 kPa−1). The developed materials were evaluated for bending and force detection applications. Thus, it is concluded that the developed P(VDF-TrFE-CFE) films are suitable for a new generation of multifunctional materials for capacitive sensing applications, including both force and deformation sensors and touchpads.



中文翻译:

高介电常数聚偏二氟乙烯-三氟乙烯-氯氟乙烯,用于电容式压力和弯曲传感器

聚偏二氟乙烯-三氟乙烯-氯氟乙烯,P(VDF-TrFE-CFE),通过改变聚合物浓度和溶剂蒸发温度通过溶剂浇铸制备样品。根据加工条件以及不同的物理化学性质(如结晶度,机械和介电性质),获得了不同的样品形态。另一方面,P(VDF-TrFE-CFE)样品的电活性β相含量和降解温度与加工条件无关。在1 kHz下,基于溶剂蒸发和210°C下的聚合物熔融,在溶液和加工条件下以15 wt%的聚合物浓度制备的样品获得的最高介电常数ε'= 40。考虑到高介电响应,-1)。对开发的材料进行了弯曲和力检测应用评估。因此,可以得出结论,所开发的P(VDF-TrFE-CFE)膜适用于用于电容感应应用的新一代多功能材料,包括力和变形传感器以及触摸板。

更新日期:2021-01-02
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