Aqueous rechargeable batteries have been considered as promising candidates to achieve the requirements for the stationary energy storage system. In recent years, numerous studies have focused on aqueous rechargeable zinc batteries (ARZBs) due to their merits of low-cost, material abundance, acceptable energy density, and environmental friendliness. The fundamental advances in energy storage of batteries are largely dependent on the electrode materials. Focusing on the recent advances of ARZBs, in this review, the reaction mechanisms, electrochemical performances, and challenges about Mn-based materials for ARZBs are systematically introduced. Meanwhile, the optimization strategies for high-performance Mn-based materials with different nanostructures, morphologies, and compositions for ARZBs are discussed as well. This paper combining reviews and perspectives of Mn-based electrodes may shed light on the development of advanced aqueous zinc batteries.

水性充电电池已被认为是实现固定式能量存储系统要求的有前途的候选者。近年来，由于其低成本，材料丰富，可接受的能量密度和环境友好的优点，许多研究都集中在水性可充电锌电池（ARZB）上。电池储能的根本进步很大程度上取决于电极材料。着眼于ARZBs的最新进展，本文综述了ARZBs的锰基材料的反应机理，电化学性能和挑战。同时，还讨论了具有不同纳米结构，形态和组成的高性能锰基材料的优化策略。