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Analysis of the Explosive Properties of Tetrasulfur Tetranitride, S4N4
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.1 ) Pub Date : 2020-12-25 , DOI: 10.1002/zaac.202000406
Ernst-Christian Koch 1 , Muhamed Suceska 2
Affiliation  

The explosive properties of tetrasulfur tetranitride, S4N4, are reviewed and analysed. S4N4 is an explosive compound with an impact sensitivity comparable to pentaerythritol tetranitrate (PETN) (Ei=4 J) but a friction sensitivity equal or even lower than lead azide (F=0.1–1 N). S4N4 has primary explosive properties. It has a working capacity greater than silver azide, AgN3, and is capable to initiate TNT. S4N4 shows an unusual non‐linear density/detonation velocity relationship which is due to different stability regimes of sulfur species present in the Chapman Jouguet zone. S4N4 is stable, non‐ageing, non‐toxic, insoluble in water and hence an interesting candidate for future lead tricinate replacement.

中文翻译:

四硫化四硫S4N4的爆炸特性分析

综述并分析了四氮化四硫S 4 N 4的爆炸特性。S 4 N 4是一种爆炸​​性化合物,其冲击敏感性可与季戊四醇四硝酸酯(PETN)媲美(E i = 4 J),但摩擦敏感性等于或低于叠氮化铅(F = 0.1-1 N)。S 4 N 4具有主要的爆炸特性。它的工作容量大于叠氮化银AgN 3,并且能够引发TNT。S 4 N 4显示出异常的非线性密度/爆速速度关系,这是由于查普曼乔格特地区存在的硫物种的稳定性不同而引起的。小号4 N 4是稳定,不老化,无毒,不溶于水的,因此是将来替代三辛酸铅的一个有趣的候选者。
更新日期:2021-02-26
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