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Recent Advances in Electrode Design Based on One-Dimensional Nanostructure Arrays for Proton Exchange Membrane Fuel Cell Applications
Engineering ( IF 10.1 ) Pub Date : 2020-12-23 , DOI: 10.1016/j.eng.2020.09.014
Shangfeng Du

One-dimensional (1D) Pt-based electrocatalysts demonstrate outstanding catalytic activities and stability toward the oxygen reduction reaction (ORR). Advances in three-dimensional (3D) ordered electrodes based on 1D Pt-based nanostructure arrays have revealed great potential in addressing the mass transfer and durability challenges of Pt/C nanoparticle electrodes for developing high-performance proton exchange membrane fuel cells (PEMFCs). This paper reviews recent progress in the field, with a focus on 3D ordered electrodes based on self-standing Pt nanowire arrays. Nanostructured thin-film catalysts are discussed along with electrodes from Pt-based nanoparticles deposited on arrays of polymer nanowires, carbon, and TiO2 nanotubes. Achievements on electrodes from Pt-based nanotube arrays are also reviewed. The importance of size, surface properties, and the distribution control of 1D catalyst nanostructures is indicated. Finally, challenges and future development opportunities are addressed regarding large electrochemical surface area (ECSA) and quantification of oxygen mass transport resistance for 1D nanostructure array electrodes.



中文翻译:

基于一维纳米结构阵列的质子交换膜燃料电池电极设计的最新进展

一维(1D)基于Pt的电催化剂表现出出色的催化活性和对氧还原反应(ORR)的稳定性。基于基于1D Pt的纳米结构阵列的三维(3D)有序电极的进展表明,在解决开发高性能质子交换膜燃料电池(PEMFC)的Pt / C纳米颗粒电极的传质和耐久性挑战方面,潜力巨大。本文回顾了该领域的最新进展,重点是基于自立式Pt纳米线阵列的3D有序电极。讨论了纳米结构的薄膜催化剂,以及沉积在聚合物纳米线,碳和TiO 2阵列上的Pt基纳米颗粒的电极纳米管。还回顾了基于Pt的纳米管阵列在电极上的成就。指出了尺寸,表面性质和一维催化剂纳米结构分布控制的重要性。最后,针对一维纳米结构阵列电极的大电化学表面积(ECSA)和氧气传质阻力的量化,解决了挑战和未来的发展机遇。

更新日期:2020-12-23
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