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Ionic conductivity of monohydroxy alcohol liquids doped with known probe ions and analysis of the liquid structure
International Journal of Modern Physics B ( IF 1.7 ) Pub Date : 2020-12-22 , DOI: 10.1142/s0217979221500144
Gui-Hua Lu 1, 2 , Li-Na Wang 2 , Xing-Yu Zhao 2 , Yu-Fen He 2 , Yi-Neng Huang 1, 2
Affiliation  

The specific values of the conductivity [Formula: see text] and its variation with temperature [Formula: see text] of 2-pentanol and 2-methyl-1-pentanol liquids doped with different concentrations of NaI (abbreviated as 2PEN-[Formula: see text]NaI and 2M1PEN-[Formula: see text]NaI, respectively) ([Formula: see text], 1% and 5%) are measured by the commercial equipment. The results show that whether NaI is doped or not, [Formula: see text] of 2PEN-[Formula: see text]NaI and 2M1PEN-[Formula: see text]NaI all have a conductivity peak in the range of 300–350 K different from that of typical glass-formers of small molecules. In addition, [Formula: see text] goes up with increasing [Formula: see text], and the temperature corresponding to [Formula: see text] maximum increases with rising NaI content. Moreover, there is a nonlinear behavior of [Formula: see text] with [Formula: see text], i.e., with rising [Formula: see text], [Formula: see text] decreases at low-temperatures, but increases at high-temperatures. Moreover, the liquid structure and its variation with [Formula: see text] are further analyzed based on the ionic conductivity.

中文翻译:

已知探针离子掺杂一羟基醇液体的离子电导率及液体结构分析

掺杂不同浓度NaI的2-戊醇和2-甲基-1-戊醇液体(简称2PEN-[公式:见正文]NaI 和 2M1PEN-[公式:见正文]NaI,分别)([公式:见正文],1% 和 5%)由商业设备测量。结果表明,无论是否掺杂NaI,2PEN-[公式:见文]NaI的[公式:见文]NaI和2M1PEN-[公式:见文]NaI均在300~350 K范围内有一个电导峰不同于典型的小分子玻璃形成剂。此外,[公式:见文]随着[公式:见文]的增加而升高,并且[公式:见文]最大值对应的温度随着NaI含量的增加而升高。此外,[公式:见文]与[公式:见文],即随着上升[公式:见文],[公式:见文]低温时减少,高温时增加。此外,基于离子电导率进一步分析了液体结构及其随[公式:见正文]的变化。
更新日期:2020-12-22
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