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Polygon-facilitated generation of colloidal gold nanoparticles by multi-MHz ultrashort-pulse laser trains: key optical factors
Laser Physics Letters ( IF 1.4 ) Pub Date : 2020-12-18 , DOI: 10.1088/1612-202x/abd171
Sergey Kudryashov 1 , Pavel Danilov 1 , Lutz Schneider 2 , Joerg Schille 2 , Udo Loeschner 2 , Alena Nastulyavichus 1 , Nikita Smirnov 1 , Alexander Kuchmizhak 3 , Oleg Vitrik 3
Affiliation  

Generation of colloidal gold nanoparticles was for the first time studied at ultra-high, multi-MHz repetition rates of 10 ps, 1030 nm laser pulses, ablating 70 nm gold film in water at the constant average power of 270 W and focusing conditions. Ultrafast (550 m s−1) laser scanning of gold films was facilitated by a polygon reflector, provided single-shot per spot through ablation of the films. According to our hypothetical model, the rate-dependent exposure of the films at the constant average power resulted in four-fold increase of the optical density of the colloidal solutions in the interband-transition spectral range (about 400 nm) due to the increasing number of incident pulses over the fixed area of 1 cm 1 cm square, despite the decreasing ablation rate at lower, inversely-proportional fluences and dynamic overlap of plume-induced bubbles.



中文翻译:

多兆赫兹超短脉冲激光序列促进多边形产生胶体金纳米颗粒:关键的光学因素

胶态金纳米颗粒的生成是第一次以10 ps的超高,多MHz重复频率,1030 nm激光脉冲进行研究,在270 W恒定平均功率和聚焦条件下烧蚀水中70 nm金膜。超快(550 ms -1)多边形反射镜有助于对金膜进行激光扫描,通过烧蚀金膜可以使每个点单发。根据我们的假设模型,在恒定的平均功率下,薄膜的速率依赖性曝光会导致胶体溶液在带间跃迁光谱范围(约400 nm)内的光密度增加四倍。尽管在较低的,反比例的​​注量和羽流引起的气泡动态重叠的情况下,消融速率有所降低,但在1 cm 1 cm 2的固定区域上的入射脉冲的数量却有所减少。

更新日期:2020-12-18
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