A new one-pot oxidative cleavage of C(sp²)−C(sp³) bond has been explored using two complementary protocols employing Phenylselenyl bromide (PhSeBr) as well as Phenyltrimethylammonium Tribromide (PTAB), with much greater efficiency and scope. The oxidative cleavage proceeds via a dearomatization step to afford potentially useful bromonaphthols along with corresponding aldehydes. In this course, we also described the first synthesis of synthetically important azido-halo naphthaleneones.

中文翻译：

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1-(1-羟基烷基) naphthalen-2-ols 的区域选择性 C(sp2)-C(sp3) 氧化键裂解：1-叠氮基-卤代-萘-2(1H)-ones 的首次合成

使用苯基硒基溴 (PhSeBr) 和苯基三甲基三溴化铵 (PTAB) 的两种互补方案探索了 C(sp ² )-C(sp ³ ) 键的新一锅氧化裂解，具有更高的效率和范围。氧化裂解通过脱芳构化步骤进行，以提供潜在有用的溴萘酚和相应的醛。在本课程中，我们还描述了合成重要的叠氮基卤代萘的首次合成。