Green Process for 5‐(Chloromethyl)furfural Production from Biomass in Three‐Constituent Deep Eutectic Solvent,ChemSusChem

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Green Process for 5‐(Chloromethyl)furfural Production from Biomass in Three‐Constituent Deep Eutectic Solvent
ChemSusChem ( IF 7.5 ) Pub Date : 2020-12-21 , DOI: 10.1002/cssc.202002631
Binglin Chen ₁ , Zheng Li ₂ , Yunchao Feng ₁ , Weiwei Hao ₁ , Yong Sun _{1,

3,

4} , Xing Tang _{1,

3,

4} , Xianhai Zeng _{1,

3,

4} , Lu Lin _{1,

3,

4}

Affiliation

5‐(Chloromethyl)furfural (CMF), a versatile bio‐platform molecule, was first synthesized in a three‐constituent deep eutectic solvent (3c‐DES) including choline chloride, AlCl₃ ⋅ 6H₂O, and oxalic acid. In particular, 3c‐DES was conducive for the production of CMF from glucose and provided a CMF yield of 70 % at 120 °C within 30 min. In addition, CMF yields reached up to 86, 80, 30, 29, and 35 % from fructose, sucrose, cellulose, bamboo, and bamboo pulp, respectively. This study opens new avenues for the preparation of CMF.

中文翻译：

在三组分深共晶溶剂中由生物质生产5-（氯甲基）糠醛的绿色工艺

5-（氯甲基）糠醛（CMF），一个多功能生物分子的平台，在三组分深共晶溶剂（3C-DES），其包括氯化胆碱首先合成，的AlCl ₃ ⋅6H ₂ O，和草酸。特别是，3c‐DES有利于从葡萄糖生产CMF，并在120°C下30分钟内提供70％的CMF收率。此外，果糖，蔗糖，纤维素，竹子和竹浆的CMF产率分别达到86％，80％，30％，29％和35％。该研究为CMF的制备开辟了新途径。

更新日期：2021-02-11

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