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Green Process for 5‐(Chloromethyl)furfural Production from Biomass in Three‐Constituent Deep Eutectic Solvent
ChemSusChem ( IF 7.5 ) Pub Date : 2020-12-21 , DOI: 10.1002/cssc.202002631
Binglin Chen 1 , Zheng Li 2 , Yunchao Feng 1 , Weiwei Hao 1 , Yong Sun 1, 3, 4 , Xing Tang 1, 3, 4 , Xianhai Zeng 1, 3, 4 , Lu Lin 1, 3, 4
Affiliation  

5‐(Chloromethyl)furfural (CMF), a versatile bio‐platform molecule, was first synthesized in a three‐constituent deep eutectic solvent (3c‐DES) including choline chloride, AlCl3 ⋅ 6H2O, and oxalic acid. In particular, 3c‐DES was conducive for the production of CMF from glucose and provided a CMF yield of 70 % at 120 °C within 30 min. In addition, CMF yields reached up to 86, 80, 30, 29, and 35 % from fructose, sucrose, cellulose, bamboo, and bamboo pulp, respectively. This study opens new avenues for the preparation of CMF.

中文翻译:

在三组分深共晶溶剂中由生物质生产5-(氯甲基)糠醛的绿色工艺

5-(氯甲基)糠醛(CMF),一个多功能生物分子的平台,在三组分深共晶溶剂(3C-DES),其包括氯化胆碱首先合成,的AlCl 3  ⋅6H 2 O,和草酸。特别是,3c‐DES有利于从葡萄糖生产CMF,并在120°C下30分钟内提供70%的CMF收率。此外,果糖,蔗糖,纤维素,竹子和竹浆的CMF产率分别达到86%,80%,30%,29%和35%。该研究为CMF的制备开辟了新途径。
更新日期:2021-02-11
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