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Zinc content (x) induced impact on crystallographic, optoelectronic, and photocatalytic parameters of Cd1-xZnxO (0 ≤ x ≤ 1) ternary nanopowder
Materials Science and Engineering: B ( IF 3.6 ) Pub Date : 2020-12-21 , DOI: 10.1016/j.mseb.2020.115001
Chitra Bhukkal , Rajni Vats , Bindiya Goswami , Neelam Rani , Rachna Ahlawat

We have synthesized Cd1-xZnxO (0 ≤ x ≤ 1) nanopowder by co-precipitation method for its comprehensive study. The Crystalline phase is changed from rocksalt CdO to wurtzite ZnO with an increase in ‘x’. The existence of H2O, COO, CdO, and ZnO group are confirmed by FTIR. SEM analysis investigated the spherical structure for x = 0.0 & 0.2 and flakes morphology for x = 0.4 & 0.6 and hexagonal block structure for x = 0.8 & 1.0. UV–Vis spectroscopy insured the increasing trend in bandgap energy within the range 2.5 ≤ Eg ≤ 3.5 eV. PL results revealed a blue shift in excitonic and band edge emission. Methyl blue dye is being selected for decomposition using different samples of Cd1-xZnxO (0 ≤ x ≤ 1) nanopowder. It is found that sample with x = 0.8 has the highest catalytic efficiency under UV light. Moreover, higher efficiency of the ternary system is managed by its highly crystalline structure, less microstrain, large surface/volume ratio, and optical bandgap.



中文翻译:

锌含量(x)对Cd 1-x Zn x O(0≤x≤1)三元纳米粉体的晶体学,光电和光催化参数的影响

我们通过共沉淀法合成了Cd 1-x Zn x O(0≤x≤1)纳米粉体,以进行全面研究。随着“ x”的增加,结晶相从岩盐CdO变为纤锌矿ZnO。FTIR证实了H 2 O,COO ,CdO和ZnO基团的存在。SEM分析研究了x = 0.0和0.2的球形结构以及x = 0.4和0.6的薄片状形态以及x = 0.8和1.0的六角形块状结构。UV-Vis光谱中投保带隙能量的范围2.5≤E内含增加的趋势 ≤为3.5eV。PL结果显示激子和能带边缘发射发生蓝移。使用不同的Cd 1-x Zn样品选择甲基蓝染料进行分解x O(0≤x≤1)纳米粉。发现x = 0.8的样品在紫外光下具有最高的催化效率。而且,三元体系的较高效率是由其高度结晶的结构,较少的微应变,较大的表面/体积比和光学带隙来管理的。

更新日期:2020-12-22
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