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Insight into the catalytic transformation of the waste products of some edible oils (corn oil and palm oil) into biodiesel using MgO/clinoptilolite green nanocomposite
Molecular Catalysis ( IF 3.9 ) Pub Date : 2020-12-19 , DOI: 10.1016/j.mcat.2020.111340
Mohamed Gameel Basyouny , Mostafa R. Abukhadra , Khaled Alkhaledi , Ahmed M. El-Sherbeeny , Mohammed A. El-Meligy , Ahmed Tawhid Ahmed Soliman , Monis Luqman

The urgent demand for renewable, eco-friendly and safe energy resources rather than traditional fossil fuels is the most critical issue encountering in the contemporary world. The urgent demand for renewable, eco-friendly and safe energy resources rather than traditional fossil fuels is the most critical issue encountering in the contemporary world. Clinoptilolite decorated with nano MgO (MgO/CP) was synthesized as advanced hybrid structure by alkali green modification process using green tea extract. It showed significant enhancement in the surface area (324.5 m2/g), ion exchange capacity (141.5 meq/100 g), and the total basicity (4.34 mmol OH/g) which qualifies the composite as a potential basic catalyst in the transesterification reactions. The MgO/CP catalyst was applied in the transesterification of used corn oil and palm oil. The composite is of promising activity and achieved biodiesel yield of 94 % from corn oil after 120 min using 4 wt., % of it as catalyst load and 15:1 as methanol-to-oil ratio at 60 °C and stirring speed of 1250 rpm. For palm oil, the catalyst achieved a yield of 97.6 % after 150 min using 4 wt., % of it as catalyst load and 20:1 as methanol-to-oil ratio at 70 °C and stirring speed of 1250 rpm. The recyclability properties of MgO/CP green nanocomposite as basic catalyst validated significant reusing of it in the transesterification of both corn oil and palm oil with high yields. The extracted biodiesel from corn oil and palm oil matches strongly the recommended limitations by ASTM D-6751 and EN 14214 standards.



中文翻译:

使用MgO /斜发沸石绿色纳米复合材料深入研究将某些食用油(玉米油和棕榈油)的废品催化转化为生物柴油

对可再生,环保和安全能源而不是传统化石燃料的迫切需求是当代世界遇到的最关键问题。对可再生,环保和安全能源而不是传统化石燃料的迫切需求是当代世界遇到的最关键问题。以绿茶提取物为原料,通过碱绿色修饰法合成了以纳米MgO(MgO / CP)修饰的斜发沸石为高级杂化结构。它显示出显着的表面积增加(324.5 m 2/ g),离子交换容量(141.5 meq / 100 g)和总碱度(4.34 mmol OH / g)使该复合材料成为酯交换反应中潜在的碱性催化剂。MgO / CP催化剂用于废玉米油和棕榈油的酯交换反应。该复合材料具有令人鼓舞的活性,在60分钟和1250搅拌速度下,使用4 wt%的催化剂负载量和15:1的甲醇油比例,在120分钟后从玉米油中获得94%的生物柴油收率。转速 对于棕榈油,在70℃和1250 rpm的搅拌速度下,使用4%(重量)的催化剂负载量和20:1的甲醇油比,催化剂在150分钟后达到97.6%的产率。MgO / CP绿色纳米复合材料作为碱性催化剂的可循环利用特性证明了它在玉米油和棕榈油的酯交换反应中具有高收率的显着重复使用。

更新日期:2020-12-20
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