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A sulfur-tolerant phosphorus doped Pd/C catalyst for hydrogenation of 4-nitrothioanisole
Molecular Catalysis ( IF 3.9 ) Pub Date : 2020-12-19 , DOI: 10.1016/j.mcat.2020.111332
Renjie Xiong , Wenqiang Zhao , Zhiqiang Wang , Minghui Zhang

In this paper, we report a new type of sulfur resistant hydrogenation catalyst, which was obtained by simply phosphating commercial Pd/C catalyst with triphenylphosphine under H2 atmosphere at 600 °C. At this temperature, no palladium phosphides formed in XRD patterns due to the low synthetic temperature. Element analysis, N2 adsorption-desorption and ICP characterizations show that only a small amount of P has been introduced into Pd, so the phosphorus doping does not change the pore size and surface area of pristine Pd/C. XPS characterization shows that P doping can effectively prevent the substrate adsorption on Pd surface, which relieves the sulfurization rate of Pd. Hence, the phosphorus doping catalyst can fully catalyze the 4-nitrothioanisole to 4-aminothioanisole and exhibits higher activity than Pd/C, which only has 70.9 % conversion. Moreover, the phosphorus doped Pd/C catalyst has better stability than Pd/C and its activity is almost unchanged during the recycle.



中文翻译:

用于4-硝基硫代苯甲醚氢化的耐硫磷掺杂Pd / C催化剂

在本文中,我们报告了一种新型的耐硫氢化催化剂,该催化剂是通过在600°C的H 2气氛下用三苯基膦简单地使商用Pd / C催化剂磷化而获得的。在此温度下,由于合成温度低,因此没有在XRD图中形成磷化钯。元素分析,N 2吸附-解吸和ICP表征表明,Pd中仅引入了少量P,因此磷掺杂不会改变原始Pd / C的孔径和表面积。XPS表征表明,P掺杂可有效防止基底吸附在Pd表面,从而减轻Pd的硫化速率。因此,磷掺杂催化剂可以将4-硝基硫代苯甲醚完全催化为4-氨基硫代苯甲醚,并且比仅具有70.9%的转化率的Pd / C具有更高的活性。而且,掺磷的Pd / C催化剂比Pd / C具有更好的稳定性,并且其活性在再循环期间几乎不变。

更新日期:2020-12-20
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