Abstract

The review presents exhaustive information for the last 5 years on the trends and methods of research, development, and application of enantioselective voltammetric sensors on the basis of new chiral materials for the recognition of enantiomers of biologically active and medicinal compounds. Enantioselective sensors on the basis of chiral Cu, Au, Ag, Pt, and Pd nanoparticles and single crystals, mesoporous metals with molecular imprints, single-wall carbon nanotubes, smart polymers, metal–organic frameworks and supramolecular assemblies, and chiral ionic liquids are considered. Examples of the recognition and determination of enantiomers in various samples and analytical characteristics of the proposed sensors are given. Problems and prospects of using enantioselective voltammetric sensors for the chiral recognition of optically active compounds are discussed.

中文翻译：

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基于手性材料的对映选择性伏安传感器

摘要

综述提供了最近五年有关基于新手性材料的对映选择性伏安传感器的研究，开发和应用趋势和方法的详尽信息，这些新手性材料用于识别生物活性和药用化合物的对映异构体。基于手性Cu，Au，Ag，Pt和Pd纳米颗粒和单晶，具有分子印迹的中孔金属，单壁碳纳米管，智能聚合物，金属有机骨架和超分子组装以及手性离子液体的对映选择性传感器是考虑过的。给出了识别和确定各种样品中对映异构体以及所提出的传感器的分析特性的示例。