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From Dimeric to Octameric Metallo‐Supramolecular Macrocycles Based on Sterically Congested Ligand–assisted Self‐Assembly with Zn(II), Cd(II), and Fe(II)
Macromolecular Rapid Communications ( IF 4.2 ) Pub Date : 2020-12-18 , DOI: 10.1002/marc.202070054
Shengwen Guan , Hao Yu , Zhe Zhang , Xin Jiang , Junjuan Shi , Tong Lu , Chunyu Wang , Pingshan Wang , Ming Wang

Inside Front Cover: In article number 2000095 by Ming Wang and coworkers, the synthesis and self‐assembly of two sterically congested terpyridinebased ligands with asymmetrically contiguous terpyridine units is reported. The terpyridine units in these ligands show a selective coordination ability and can preferentially form a rhombus‐like intermediate to assist the formation of the final dimeric to octameric metallo‐supramolecular macrocycles.
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中文翻译:

Zn(II),Cd(II)和Fe(II)的立体拥挤配体辅助自组装,从二聚体到八聚体的金属超分子大环

内部封面:Ming Wang及其同事的文章编号2000095中,报道了两个具有不对称连续吡啶基单元的空间拥塞的基于吡啶的配体的合成和自组装。这些配体中的三联吡啶单元具有选择性配位能力,可以优先形成菱形中间体,以帮助形成最终的二聚体到八聚体的金属-超分子大环。
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更新日期:2020-12-18
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