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Biomass of ryegrass from field experiments: toward a cost-effective and efficient biosourced catalyst for the synthesis of Moclobemide
Green Chemistry Letters and Reviews ( IF 5.8 ) Pub Date : 2020-12-16 , DOI: 10.1080/17518253.2020.1856943
Marie Hechelski 1 , Christophe Waterlot 1 , Pierrick Dufrénoy 2, 3 , Brice Louvel 1 , Adam Daïch 3 , Alina Ghinet 2, 4, 5
Affiliation  

ABSTRACT

Lolium perenne L., a common plant perennial ryegrass from Europe, northern Africa and Asia, was selected to produce biomass under field conditions. The biomass of this nonfood crop was from a highly contaminated agricultural soil by potentially toxic metals (Cd, Pb and Zn) with the aim of maintaining the agricultural vocation of these soils. In this perspective and in view of the metal concentration (Cd, Pb, Zn, macro- and micro-nutrients), the biomass of ryegrass was considered as a bio 'ore' resource and was used as the starting material for the preparation of contemporary biosourced catalysts. The heterogeneous catalyst from the current work was successfully used in the synthesis of Moclobemide, used to treat anxiety and major depressive episodes. Through this original approach, Moclobemide was synthesized in one step, in 80% yield under solvent-free conditions.



中文翻译:

来自野外实验的黑麦草生物量:寻求一种经济高效的生物来源催化剂,用于合成莫氯贝米

摘要

黑麦草L.是一种来自欧洲,北非和亚洲的常见植物多年生黑麦草,被选择用于在田间条件下生产生物量。这种非粮食作物的生物量来自高度污染的农业土壤,被潜在有毒金属(镉,铅和锌)污染,目的是维持这些土壤的农业生产能力。从这个角度出发,鉴于金属浓度(Cd,Pb,Zn,大量和微量营养元素),黑麦草的生物量被认为是一种生物“矿石”资源,并被用作制备当代植物的原料。生物来源的催化剂。当前工作中的非均相催化剂已成功用于莫氯贝胺的合成中,用于治疗焦虑症和重度抑郁发作。通过这种原始方法,一步合成了莫氯贝米,

更新日期:2020-12-17
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