Effective Tools for the Metal‐Catalyzed Regiodivergent Direct Arylations of (Hetero)arenes,The Chemical Record

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Effective Tools for the Metal‐Catalyzed Regiodivergent Direct Arylations of (Hetero)arenes
The Chemical Record ( IF 7.0 ) Pub Date : 2020-12-17 , DOI: 10.1002/tcr.202000145
Hai‐Yun Huang ₁ , Amal Benzai ₁ , Xinzhe Shi ₁ , Henri Doucet ₁

Affiliation

The direct functionalization of two different C−H bonds of the same organic molecule using different procedures ‐ also called regiodivergent C−H bond functionalization ‐ currently represents an important research topic in organic chemistry, as it demonstrates the versatility of C−H bond functionalization methodology. Over the last decade, the number of tools to control such regiodivergent C−H bond functionalizations has increased significantly. In this account, we will present the various tools that allowed us to arylate different positions of various (hetero)arenes, via a C−H bond functionalization, using palladium or ruthenium catalysis.

中文翻译：

金属催化（杂）芳烃区域发散性直接芳基化的有效工具

使用不同的方法将同一有机分子的两个不同的CH键直接官能化-也称为区域发散的CH键功能-目前代表了有机化学中的重要研究课题，因为它证明了CH键功能化方法的多功能性。在过去的十年中，控制这种区域发散性CH键功能化的工具的数量已大大增加。在此说明中，我们将介绍各种工具，这些工具使我们能够使用钯或钌催化，通过CH键官能化来芳构各种（杂）芳烃的不同位置。

更新日期：2021-02-18

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