当前位置: X-MOL 学术Isr. J. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Metal Free Amino-Oxidation of Electron Rich Alkenes Mediated by an Oxoammonium Salt
Israel Journal of Chemistry ( IF 2.3 ) Pub Date : 2020-12-15 , DOI: 10.1002/ijch.202000080
Alexandra M. Millimaci 1 , Rowan I. L. Meador 1 , Sara J. Dampf 1 , John D. Chisholm 1
Affiliation  

4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium tetrafluoroborate (Bobbitt's salt) effectively activates electron rich alkenes and promotes the addition of anilines. This transformation provides a direct, transition metal free method for amino-oxidation of alkenes under mild conditions. The relative stereochemistry of the amino-oxidation is influenced by solvent effects, with both the syn and anti amino-oxidation products being accessible from identical starting materials.

中文翻译:

氧铵盐介导的富电子烯烃的无金属氨基氧化

4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium 四氟硼酸盐(波比特盐)有效激活富电子烯烃并促进苯胺的添加。这种转变为烯烃在温和条件下的氨基氧化提供了一种直接的、无过渡金属的方法。氨基氧化的相对立体化学受溶剂效应的影响,顺式和抗氨基氧化产物都可以从相同的起始材料中获得。
更新日期:2020-12-15
down
wechat
bug