Thionation of the 2‐λ5‐Phosphaquinolin‐2‐one Scaffold with Lawesson's Reagent,Israel Journal of Chemistry

当前位置： X-MOL 学术 › Isr. J. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Thionation of the 2‐λ5‐Phosphaquinolin‐2‐one Scaffold with Lawesson's Reagent
Israel Journal of Chemistry ( IF 2.3 ) Pub Date : 2020-12-14 , DOI: 10.1002/ijch.202000085
Jeremy P. Bard ₁ , J. Nolan McNeill ₁ , Gabrielle I. Warren ₁ , Lev N. Zakharov ₂ , Darren W. Johnson ₁ , Michael M. Haley ₁

Affiliation

Lawesson's reagent is one of the most common thionating reagents that has found use for several decades on a variety of carbonyl systems. Herein, we report the transformation of the 2‐λ⁵‐phosphaquinolin‐2‐one structure to its respective 2‐λ⁵‐phosphaquinolin‐2‐thione derivative. Solution‐state characterization of both P−OPh and P−Ph thio analogues, as well as solid‐state structures for the latter system, are reported.

中文翻译：

用Lawesson试剂对2-λ5-Phosphaquinolin-2-one支架进行电离

Lawesson的试剂是最常见的硫代试剂之一，已在多种羰基体系中使用了数十年。在本文中，我们报道了2-λ的转变⁵ -phosphaquinolin -2-酮结构到其相应的2-λ ⁵ -phosphaquinolin -2-硫酮衍生物。报告了P-OPh和P-Ph硫代类似物的溶液状态表征，以及后者系统的固态结构。

更新日期：2020-12-14

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11