Abstract

A method has been presented for solving the inverse problem of chemical kinetics based on steady-state experimental data with different initial conditions (multiexperiments) taking into account measurement errors in an open nonisothermal gradientless reactor. Examples of using the method to determine the intervals of the physical values of rate constants for the stages of multistage nonlinear reactions have been given. The effect of measurement errors on the accuracy and stability of the method has been evaluated.

中文翻译：

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基于稳态数据的非等温无梯度反应器化学动力学反问题的求解方法

摘要

考虑到开放式非等温无梯度反应器中的测量误差，已经提出了一种基于具有不同初始条件（多次实验）的稳态实验数据来解决化学动力学逆问题的方法。给出了使用该方法确定多阶段非线性反应各阶段速率常数的物理值区间的示例。已经评估了测量误差对方法准确性和稳定性的影响。