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A novel effect of combining microorganisms and graphene oxide for solidifying simulated nuclides strontium
Journal of Environmental Radioactivity ( IF 1.9 ) Pub Date : 2020-12-13 , DOI: 10.1016/j.jenvrad.2020.106507
Li Zhou , Tao Chen , Guoliang He , Xinglian Jin , Sheng Liu , Jie Lian , Fan Yang , Xianyin Li , Jialiang Zhang , Xinsheng He , Wenkun Zhu

Inspired by microbial diagenesis and mounding, microbial mineralization technology has been widely used in the treatment of heavy metal and radionuclide contamination. S. pasteurii can decompose urea as a source of energy to produce CO32− in the microbial mineralization system. Therefore, strontium-contaminated radioactive wastewater can be effectively treated by combining CO32− with surrounding strontium ions (Sr2+) to form strontium carbonate (SrCO3). Herein, we investigated how the concentration of graphene oxide (GO) and mineralization time influence the morphology of SrCO3 and the mineralization efficiency. GO was used as a crystal regulator to solidify the radionuclide strontium in the microbial mineralization system to obtain large-scale rock-like SrCO3 minerals. The results showed that GO can adsorb the surrounding Sr2+ with oxygen-containing functional groups on its surface to form SrCO3 complexes, directly influencing the morphology and consolidation percentage of SrCO3. Considering the leaching behaviour of nuclides, we further studied the stability of consolidated SrCO3 minerals. The results indicated that the presence of GO improved the stability of the mineralized samples obtained in the microbial mineralization system.



中文翻译:

微生物与氧化石墨烯混合固结模拟核素锶的新效果

受微生物成岩作用和堆积作用的启发,微生物矿化技术已被广泛用于重金属和放射性核素污染的处理。巴氏酵母可以分解尿素作为能源,在微生物矿化系统中产生CO 3 2-。因此,通过将CO 3 2-与周围的锶离子(Sr 2+)结合形成碳酸锶(SrCO 3),可以有效地处理被锶污染的放射性废水。本文中,我们研究了氧化石墨烯(GO)的浓度和矿化时间如何影响SrCO 3的形貌和矿化效率。GO被用作晶体调节剂,以固化微生物矿化系统中的放射性核锶,从而获得大规模的岩石状SrCO 3矿物。结果表明,GO可吸附周围的Sr 2+与含氧的官能团在其表面上,以形成的SrCO 3种配合物,直接影响的SrCO的形态和合并百分比3。考虑到核素的浸出行为,我们进一步研究了固结SrCO 3矿物的稳定性。结果表明GO的存在改善了在微生物矿化系统中获得的矿化样品的稳定性。

更新日期:2020-12-14
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