Physica B: Condensed Matter ( IF 2.8 ) Pub Date : 2020-12-11 , DOI: 10.1016/j.physb.2020.412704 Rida Ahmed , Renjun Si , Sajid ur Rehman , Yi Yu , Qiuju Li , Chunchang Wang
Bi1-x(Sr0·5Pb0.5)xFeO3 with x = 0.1 and 0.3 were synthesized by solid-state reaction method. The dielectric properties of the samples have been investigated in the temperature range from −100 to 300 °C. The colossal dielectric constant (CDC) behavior was observed in temperature range from 50 to 200 °C and frequency range from 102 Hz to 103 Hz. The CDC behavior is composed of two relaxation processes with the lower temperature relaxation being a dipolar relaxation caused by the hopping of oxygen vacancies and the higher temperature one being a Maxwell-Wagner relaxation caused by hopping oxygen vacancies blocked by grain boundaries. In the temperature range beyond 200 °C, a ferroelectric-phase-transition-induced dielectric anomaly with an extremely huge intensity over 106 was observed in both samples. (Sr, Pb) co-doping in the place of Bi significantly shift the Curie temperature towards a low temperature of 263 and 243 °C for the samples with x = 0.1 and 0.3, respectively.
中文翻译:
Bi 1- x(Sr 0·5 Pb 0.5)x FeO 3中的高介电常数和低温铁电相变
毕1- X的(Sr 0·5的Pb 0.5)X的FeO 3与X = 0.1和0.3,通过固相反应法合成。已在-100至300°C的温度范围内研究了样品的介电性能。在50至200°C的温度范围和10 2 Hz至10 3的频率范围内观察到巨大的介电常数(CDC)行为 赫兹。CDC行为由两个弛豫过程组成,较低的温度弛豫是由氧空位的跃迁引起的偶极弛豫,而较高的温度是由跃迁的氧空位被晶界阻塞引起的麦克斯韦-瓦格纳弛豫。在超过200°C的温度范围内,在两个样品中都观察到铁电相变引起的介电异常,强度异常超过10 6。(Sr,Pb)共掺杂代替Bi分别将x = 0.1和0.3的样品的居里温度移向263和243°C的低温。